Questions-
Why O--R having more --I Effect than
O--H ?
Actually The main cause of more --I effect of OR than OH is electronegativity difference.
I will give you right and exact reason of this.
Electronegativity of some element---
H-2
C-2.5
N-3.0
O-3.5
F- 4.0
Actually electronegativity difference of
O--C is 1.0
while
electronegativity difference of O--H is 1.5 .
EXPLANATION---
● FOR [ O--H ]---
oxygen attracts shared pair of electron of O-H bond more strongly .Now electron density around oxygen increases. So due to excess of electron the electron attracting tendency od O decreses .due to which --I Effect of O--H bond is is less.
● FOR [ O--R ]--- oxygen attracts shared pair electron of O-H bond relatively less strongly .bcz carbon and oxygen having less difference in electronegativity .Now electron density around oxygen relatively decreases. Hence due to deficiency of electron in O , the electron attracting tendency od O increses .due to which --I Effect of O--R bond is is less.
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